By Joseph J. Katz, Lester R. Morss, Norman Edelstein, Jean Fuger
The Chemistry of the Actinide and Transactinide parts is a modern and definitive compilation of chemical homes of the entire actinide components, in particular of the technologically very important parts uranium and plutonium, in addition to the transactinide parts. as well as the great remedy of the chemical houses of every point, ion, and compound from atomic quantity 89 (actinium) via to 109 (meitnerium), this multi-volume paintings has really expert and definitive chapters on digital thought, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic homes, the metals, coordination chemistry, separations, and hint research. a number of chapters take care of environmental technological know-how, secure dealing with, and organic interactions of the actinide parts. The Editors invited groups of authors, who're lively practitioners and well-known specialists of their uniqueness, to jot down every one bankruptcy and feature endeavoured to supply a balanced and insightful therapy of those attention-grabbing parts on the frontier of the periodic desk. as the box has accelerated with new spectroscopic thoughts and environmental concentration, the paintings encompasses 5 volumes, every one of which teams chapters on comparable issues. All chapters symbolize the present country of analysis within the chemistry of those components and similar fields.
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Extra resources for The Chemistry of the Actinide and Transactinide Elements (5 Volume Set) (v. 1-5)
Handbook on the Physics and Chemistry of Rare Earths, North-Holland, Amsterdam, New York; Elsevier Science, New York, NY, vols 17–19, 1993–1994. Handbook on the Physics and Chemistry of the Actinides, North-Holland, Amsterdam, New York; Elsevier Science, New York, NY, 1984–1991, 6 volumes. Hoffman, Darleane C. (2002) Advances in Plutonium Chemistry, 1967–2000, American Nuclear Society, La Grange Park, IL. Kaltsoyannis, N. and Scott, P. (1999) The f Elements, Oxford University Press, Oxford. Katz, J.
W. (1965) Plutonium, NAS-NS-3058; Penneman, R. A. and Keenan, R. K. (1960) Americium and Curium, NAS-NS-3006; Higgins, G. H. (1960) The Transcurium Elements, NAS-NS-3031; Roberts, R. , Choppin, G. , and Wild, J. F. (1986). Uranium, Neptunium and Plutonium, An Update, NA-NS-3063. htm. Navratil, J. D. and Schulz, W. W. ) (1980) Actinide Separations (ACS Symp. Ser. 117), American Chemical Society, Washington, DC. Additional suggested readings 17 Navratil, J. D. and Schulz, W. W. ) (1981) Transplutonium Elements – Production and Recovery (ACS Symp.
Rao and Gupta (1961) studied the adsorption of 228Ra and 228Ac onto sintered glass and paper, and found that the adsorption of 228Ac onto the glass increased with pH and time of aging. They studied the phenomenon by Actinium 42 centrifugation; the 228Ac fraction could be centrifuged at pH ! 5. Paper chromatography showed that the 228Ac was immobile at a pH of 3 and higher, whereas Ba remained in solution. They concluded that the 228Ac formed radiocolloids at pH ! 5. 5 Analytical chemistry of actinium Sedlet (1964) published a complete set of procedures for analytical chemistry of actinium, primarily radiochemical procedures for 227Ac.